Liverpool struck three goals in eight first-half minutes to inflict a second defeat on leaders Chelsea, with Rhys Williams, pictured, scoring for the Reds after making his UEFA Champions League debut in midweek.
Jake Cain netted his third free-kick of the season and Liam Millar converted a penalty for Liverpool, with the Blues only able to muster a consolation through Bryan Fiabema's 81st-minute spot-kick.
See: Liverpool report | Chelsea report
Elsewhere, Manchester City made it three wins in a row as they came from behind to beat 10-man Arsenal, while in Division 2, goals by Ian Poveda and Raphinha secured a 2-0 victory for Leeds United over leaders Norwich City.
Click on the matches below for more details, with line-ups and stats.
Matchweek 6 results
Division 1
HT:
Half Time:
0-0
Anthony Elanga 75'
Ethan Galbraith 90 +7' (pen)
Ellis Simms 60'
Assists
Joe Hugill 75'
Division 2
HT:
Half Time:
2-3
Tyrese Francois 17'
Ryan De Havilland 24', 32'
Assists
Elliot Embleton 16'
Terry Ablade 17', 24'
Tyrese Francois 32'
HT:
Half Time:
1-0
Christian Benteke 45 +2'
Scott Banks 47'
Taylor Perry 69'
Assists
Sam Woods 45 +2'
Brandon Pierrick 47'
HT:
Half Time:
2-1
Moritz Bauer 37', 45 +1', 72'
Ethon Varian 90 +2'
Jayden Onen 5'
Assists
Thibaud Verlinden 37', 45 +1'
Ethon Varian 72'